Acid Base Titration
Standardization of NaOH: Acid Base Titration

In this problem, you will accurately determine the concentration of a solution of sodium hydroxide (NaOH) using a 0.500M potassium hydrogen phthalate (KHP) standard solution. Acid-base indicator phenophthalein is added in its (colorless) acidic form to a precise volume sample of KHP. The base NaOH is slowly added to the sample of KHP. Once all the KHP has reacted with the base, the first excess drop of NaOH will cause the indicator to convert to its basic (pink) form. The exact concentration of the NaOH solution can then be calculated. Experimental Procedure: Retrieve the KHP, 1M NaOH solution, and the phenolphthalein from the stockroom. Double click on the Solutions cabinet to display the list of solutions. Double click on each solution to place it on the workbench. Note the volume of KHP, which can be found in the Solution Info window. Retrieve a disposable pipette and a 50 mL buret. Click on the glassware button on the action bar. Click on the necessary glassware that appears on the drop-down menu. Use a disposable pipette to add a small amount (~0.3 mL) of indicator to the KHP solution. Drag the pipette onto the indicator solution so the mouse pointer is inside the edges of the source container (the pipette). When the pipette is above the indicator solution, briefly click the Withdraw button on the transfer bar. Then drag the pipette onto the KHP solution so that the mouse pointer is within the edges of the flask and briefly click the Pour button on the transfer bar. Fill the buret with NaOH solution. In the same manner as Step 4, drag the flask of NaOH onto the buret so the mouse pointer is inside the edges of the recipient container (the buret). When the flask is tilted above the buret, click and hold down the Pour button in the transfer bar. When you release the mouse button, the Solution Info window will allow you to infer how much has been transferred. Titrate small volumes (~ 0.5 mL or less) of NaOH from the buret into the KHP until a slight color change occurs. Note the volume of NaOH used, which can be found in the Solution Info window. You can check this by using Precise Transfer Mode instead of Realistic. Under the Tools menu, select Precise Transfer, and instead of clicking and holding the Pour button, type in 13.23 mL and click the Pour button once. The end point occurs at 13.23 mL, and the concentration of NaOH is 0.9445 M. You should see a very light pink end point.